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3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 1 of 17 safety data sheet c opy right, 2011, 3m company all rights reserved. copying and/or dow nloading of this information for the purpose of properly utilising 3m products is allow ed provided that: (1) the information is copied in full w ith no changes unless prior written agreemen t is obtained from 3m, ve (2) neither the copy nor the original is resold or otherw ise distributed w ith the intention of earning a profit thereon. document group: 22 - 7859 - 6 version number: 6.04 revision date: 29/07/2011 supersedes date: 09/05/2011 t ransportation version number: 1.00 (14/04/2010) this safety data sheet has been prepared in accordance w ith the reach regulation (ec) 1907/2006 and its modifications. section 1: identification of the substance/mixture and of the company/undertaking 1 .1. product identifier 3m scotch - weld tl70 anaerobic threadlocker product identification numbers gs - 2000 - 4405 - 4 gs - 2000 - 4406 - 2 gs - 2000 - 4407 - 0 gs - 2000 - 4477 - 3 gs - 2000 - 4478 - 1 gs - 2000 - 4496 - 3 gs - 2000 - 4636 - 4 gs - 2000 - 4637 - 2 gs - 2000 - 4695 - 0 gs - 2000 - 4992 - 1 gs - 2000 - 4993 - 9 gs - 2000 - 4994 - 7 gs - 2000 - 4995 - 4 gs - 2000 - 4996 - 2 gs - 2000 - 5025 - 9 gs - 2000 - 5309 - 7 gs - 2000 - 5331 - 1 1.2. relevant identified uses of the substance or m ixture and uses advised against identified uses s tructural adhesive. 1.3. details of the supplier of the substance or mixture address: 3m united kingdom plc, 3m centre, cain road, bracknell, berkshire, rg12 8ht. e mail: tox.uk@mmm.com website: www.3m.com/uk 1.4. em ergency telephone number + 44 (0)1344 858 000 section 2: hazard identification 2.1. classification of the substance or m ixture dangerous substances(67/548/eec)/preparations(1999/45/ec) directive indication of danger irritant. sensitising 2.2. label elem ents d angerous substances(67/548/eec)/preparations(1999/45/ec) directive
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 2 of 17 symbols xi irritant. contains: 2 - hy droxypropyl methacrylate; methacrylic acid, monoester w ith propane - 1,2 - diol; 2,2' - ethylenedioxydiethyl dimethacrylate risk phrases r36/37/38 i rritating to eyes, respiratory system and skin. r43 may cause sensitisation by skin contact. safety phrases s24 avoid contact with skin. s37 wear suitable gloves. 2.3. other hazards none known. section 3: composition/information on ingredients ingredient cas nbr eu inventory % by wt classification 2,2' - ethylenedioxydiethyl dimethacrylate 109 - 16 - 0 einecs 203 - 652 - 6 40 - 70 r43 (self classified) skin sens. 1, h317; aquatic ac ute 1, h400,m=1; aquatic chronic 3, h412 (self classified) p olyester resin trade secret 15 - 40 methacrylic acid, monoester with propane - 1,2 - diol 27813 - 02 - 1 einecs 248 - 666 - 3 1 - 5 xi:r36 - 37; r43 (vendor) ey e irrit. 2, h319; skin sens. 1, h317; stot se 3, h335 (vendor) , - dimethylbenzyl hydroperoxide 80 - 15 - 9 einecs 201 - 254 - 7 1 - 5 o:r7; t:r23; c:r34; xn:r21 - 22 - 48/20; xn:r48/22; n:r51/53 (eu) org. perox. ef, h242; acute tox. 2, h330; acute tox. 3, h311; acute tox. 4, h302; skin corr. 1b, h314; stot se 3, h335; stot re 1, h372; aq uatic chronic 2, h411 (clp) acrylic acid 79 - 10 - 7 einecs 201 - 177 - 9 1 - 5 c:r35; xn:r20 - 21 - 22; n:r50; r10 - nota d (eu) flam. liq. 3, h226; acute tox. 3, h331; acute tox. 3, h311; ac ute tox. 4, h302; skin corr. 1a, h314; stot se 3, h335; aq uatic acute 1, h400,m=1 - nota d (clp) 2 - hy droxypropyl methacrylate 923 - 26 - 2 einecs 213 - 090 - 3 1 - 5 xi:r36; r43 - nota c,d (eu )
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 3 of 17 ey e irrit. 2, h319; skin sens. 1, h317 - nota c,d (clp) 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide 81 - 07 - 2 einecs 201 - 321 - 0 0.5 - 1.5 cumene 98 - 82 - 8 einecs 202 - 704 - 5 0.1 - 1 xn:r65; xi:r37; n:r51/53; r10 - nota 4 (eu) flam. liq. 3, h226; asp. tox. 1, h304; stot se 3, h335; aq uatic chronic 2, h411 - nota c (clp) 2' - phenylacetohydrazide 114 - 83 - 0 einecs 204 - 055 - 3 0.1 - 1 xi:r36 - 37 - 38; r43 (vendor) xn:r21 - 22 (self classified) skin irrit. 2, h315; eye irrit. 2, h319; sk in sens. 1, h317; stot se 3, h335 (vendor) ac ute tox. 3, h311; acute tox. 3, h301 (self classified) n,n - dimethyl - p - toluidine 99 - 97 - 8 einecs 202 - 805 - 4 0.05 - 0.99 t:r23 - 24 - 25; r33; r52/53 - nota c (eu) ac ute tox. 3, h331; acute tox. 3, h311; acute tox. 3, h301; stot re 2, h373; aquatic chronic 3, h412 - nota c (clp) optical brightener trade secret 0.05 - 0.15 p lease see section 16 for the full text of any r phrases and h statements referred to in this section please refer to section 15 for the any applicable notas that have been applied to the above components f or information on ingredient occupational exposure limits or pbt or vpvb status, see sections 8 and 12 of this sds section 4: first aid measures 4.1. description of first aid measures eye contact immediately flush with large amounts of water. remove c ontact lenses if easy to do. continue rinsing. get medical attention. skin contact immediately wash with soap and w ater. remove contaminated clothing and wash before reuse. if signs/symptoms develop, get medical attention. inhalation r em ove person to fresh air. if you feel unwell, get medical attention. if swallowed rinse mouth. if you feel unwell, get medical attention. 4.2. most im portant symptoms and effects, both acute and delayed s ee section 11.1 information on toxicological effects 4.3. indication of any immediate m edical attention and special treatm ent required not applicable
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 4 of 17 section 5: fire - fighting measures 5.1. extinguishing media i n case of fire: use a fire fighting agent suitable for flammable liquids or gases such as dry chemical or carbon dioxide. 5.2. special hazards arising from the substance or mixture closed containers exposed to heat from fire may build pressure and explod e. hazardous decom position or by - products substance condition carbon monoxide. during combustion. carbon dioxide. during combustion. oxides of nitrogen. during combustion. oxides of sulphur. during combustion. 5.3. advice for fire - fighters no unusual fire or explosion hazards are anticipated. section 6: accidental release measures 6.1. personal precautions, protective equipm ent and emergency procedures e vacuate area. ventilate the area w ith fresh air. for large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapours, in accordance w ith good industrial hygiene practice. warning: a motor could be an ignition sour ce and could cause flammable gases or vapours in the spill area to burn or explode. refer to other sections of this sds for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. en vironm ental precautions for larger spills, cover drains and build dykes to prevent entry into sewer systems or bodies of water. avoid release to the environment. 6.3. methods and m aterial for containm ent and cleaning up contain spill. working from aroun d the edges of the spill inward, cover w ith bentonite, vermiculite, or commercially available inorganic absorbent material. mix in sufficient absorbent until it appears dry. remember, adding an absorbent material does not remove a toxic, corrosivity or fl ammability hazard. collect as much of the spilled material as possible. place in a closed container approved for transportation by appropriate authorities. clean up residue with an appropriate solvent selected by a qualified and authorised person. venti late the area with fresh air. read and follow safety precautions on the solvent label and safety data sheet. seal the container. dispose of collected material as soon as possible. 6.4. reference to other sections refer to section 8 and section 13 for mo re information section 7: handling and storage 7.1. precautions for safe handling f or industrial or professional use only. do not breathe dust/fume/gas/mist/vapours/spray. do not get in eyes, on skin, or on clothing. do not eat, drink or smoke when using this product. wash thoroughly after handling. contaminated w ork clothing should not be allow ed out of the w orkplace. avoid release to the environment. wash contaminated clothing before reuse. avoid contact with oxidising agents (eg. chlorine, chromic acid etc.) 7.2. conditions for safe storage including any incompatibilities stor e in a w ell - ventilated place. keep container tightly closed. store aw ay from heat. protect from sunlight. store away from oxidising agents.
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 5 of 17 7.3. specific end use(s) see information in section 7.1 and 7.2 for handling and storage recommendations. see section 8 for exposure controls and personal protection recommendations. section 8: exposure controls/personal protection 8.1 control param eters occupational exposure limits ingredient cas nbr agency limit type additional comments cumene 98 - 82 - 8 h ealth and safety comm. (uk) twa:125 mg/m3(25 ppm );stel:250 mg/m3(50 ppm ) skin notation health and safety comm. (uk) : uk health and safety commission twa: time - weighted - average stel: short term exposure limit ppm: parts per million mg/m3: milligrams per cubic metre ceil: ceiling 8.2. exposure controls 8.2.1. engineering controls c uring enclosures must be exhausted to outdoors or to a suitable emission control device. use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant exposure limits and/or control dust/fume/gas/mist/va pours/spray. if ventilation is not adequate, use respiratory protection equipment. 8.2.2. personal protective equipment (ppe) eye/face protection wear eye/face protection. the follow ing eye protection(s) are recommended: safety glasses with side shields . indirect vented goggles. skin/hand protection wear protective gloves. gloves made from the following material(s) are recommended: butyl rubber. fluoroelastomer neoprene. nitrile rubber. polymer laminate respiratory protection i n case of inadequate ventilation w ear respiratory protection. select one of the following approved respirators based on airborne concentration of contaminants and in accordance with regulations: half face piece or full face air - purifying respirator w ith or ganic vapour cartridges. half facepiece or fullface pressure demand self - contained breathing apparatus. section 9: physical and chemical properties 9.1. inform ation on basic physical and chemical properties
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 6 of 17 physical state liquid. s pecific physical form: thixotropic liquid. appearance/odour green liquid. slightly sweet odour. ph not applicable. boiling point/boiling range >=204.4 oc melting point not applicable. flamm ability (solid, gas) not classified explosive properties n ot classified oxidising properties not classified flash point >=100 oc [ test method: closed cup] flamm able limits(lel) no data available. flamm able limits(uel) no data available. vapour pressure <=13.3 pa [@ 20 oc ] relative density 1.04 [ ref std: w at er=1] water solubility slight (less than 10%) partition coefficient: n - octanol/water no data available. evaporation rate no data available. evaporation rate negligible vapour density 1.01 [ ref std: air=1] viscosity 0.5 pa - s [@ 23 oc ] d ensity 1.04 g/ml 9.2. other inform ation hazardous air pollutants 1.6 - 1.7 % w eight volatile organic com pounds (voc) no data available. voc less h2o & exempt solvents no data available. section 10: stability and reactivity 1 0.1 reactivity this material may be reactive with certain agents under certain conditions - see the remaining headings in this section 10.2 chem ical stability stable. 10.3 possibility of hazardous reactions hazardous polymerisation may occur. may o ccur in large quantities only. 10.4 conditions to avoid heat. light. 10.5 incom patible materials strong oxidising agents. avoid temperatures in excess of 65 c. avoid contamination. 10.6 hazardous decom position products substance condition n one known.
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 7 of 17 section 11: toxicological information t he information below m ay not be consistent with the material classification in section 2 if specific ingredient classifications are m andated by a competent authority. in addition, toxicological data on ingredients m ay not be reflected in the m aterial clas sification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labelling, an ingredient may not be available for exposure, or the data m ay not be relevant to the m aterial as a whole. 11.1 inform ation on toxicological effects signs and sympto ms of exposure based on test data and/or inform ation on the components, this m aterial may produce the following health effects: eye contact severe eye irritation: signs/symptoms may include significant redness, swel ling, pain, tearing, cloudy appearance of the cornea, and impaired vision. skin contact s kin irritation: signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. allergic skin reaction (non - photo induced): signs/symptoms may include redness, swelling, blistering, and itching. inhalation r espiratory tract irritation: signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. may cause target organ effects after inhalation. ingestion gastrointestinal irritation: signs/symptoms may include a bdom inal pain, stomach upset, nausea, vomiting and diarrhoea. may cause target organ effects after ingestion. target organ effects: prolonged or repeated exposure may cause: neurological effects: signs/symptoms may include personality changes, lack of c oordination, sensory loss, tingling or numbness of the extremities, w eakness, tremors, and changes in blood pressure and heart rate. respiratory effects: signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rat e, bluish coloured skin (cyanosis), sputum production, changes in lung function tests, and respiratory failure. toxicological data acute toxicity nam e route species value un ghs classification overall product ingestion n o test data available; calculated ate >5000 mg/kg not classified (28.9% unknown) 2,2' - ethylenedioxydiethyl dim ethacrylate ingestion rat ld50 10837 mg/kg not classified 2 - hy droxypropyl methacrylate ingestion rat ld50 > 2,000 mg/kg not classified m ethacrylic acid, monoester with propane - 1,2 - diol derm al rabbit ld50 > 5,000 mg/kg not classified methacrylic acid, monoester with propane - 1,2 - diol ingestion rat ld50 11200 mg/kg not classified acrylic acid derm al rabbit ld50 295 mg/kg category3 a crylic acid inhalation - vapor (4 hours) rat lc50 4 mg/l category3
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 8 of 17 acrylic acid ingestion rat ld50 1250 mg/kg category4 , - dimethylbenzyl hydroperoxide derm al rat ld50 500 mg/kg category3 , - dimethylbenzyl hydroperoxide inhalation - vapor (4 hours) rat lc50 1 mg/l category2 , - dimethylbenzyl hydroperoxide ingestion rat ld50 382 mg/kg category4 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide ingestion mouse ld50 17000 mg/kg not classified 2' - phenylacetohydrazide derm al ld50 estimated to be 200 - 1000 mg/kg category3 2' - phenylacetohydrazide ingestion mouse ld50 270 mg/kg category3 cumene derm al rabbit ld50 > 3160 mg/kg category5 cumene inhalation - vapor (4 hours) rat lc50 39 mg/l category5 cumene ingestion rat ld50 1400 mg/kg category4 n,n - dimethyl - p - toluidine derm al rabbit ld50 > 2,000 mg/kg category5 optical brightener derm al rabbit ld50 > 2,000 mg/kg category5 n,n - dimethyl - p - toluidine inhalation - dust/mist (4 hours) rat lc50 1 mg/l category4 n,n - dimethyl - p - toluidine ingestion rat ld50 1650 mg/kg category4 optical brightener ingestion rat ld50 > 2,000 mg/kg category5 at e = acute toxicity estimate skin corrosion/irritation nam e species value un ghs classification overall product no test data available; calculated to be i rritant category 2 2,2' - ethylenedioxydiethyl dim ethacrylate mild irritant category 3 2 - hy droxypropyl methacrylate no data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid corrosive category 1b , - dimethylbenzyl hydroperoxide corrosive category 1c 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylacetohydrazide no data available cumene minimal irritation not classified n,n - dimethyl - p - toluidine no data available o ptical brightener no data available serious eye damage/irritation nam e species value un ghs classification overall product no test data available; calculated to be severe irritant category 2a 2,2' - ethylenedioxydiethyl dim ethacrylate m oderate irritant category 2b 2 - hy droxypropyl methacrylate no data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid corrosive category 1
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 9 of 17 , - dimethylbenzyl hydroperoxide severe irritant category 2a 1 ,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylacetohydrazide no data available cumene mild irritant not classified n,n - dimethyl - p - toluidine no data available optical brightener no data available skin sensitisation nam e s pecies value un ghs classification overall product no test data available. category 1 based on com ponent data 2,2' - ethylenedioxydiethyl dim ethacrylate sensitising category 1 2 - hy droxypropyl methacrylate no data available m ethacrylic acid, monoester with propane - 1,2 - diol sensitising category 1 acrylic acid som e positive data exist, but the data are not sufficient for classification not classified , - dimethylbenzyl hydroperoxide no data available 1 ,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylacetohydrazide no data available cumene not sensitizing not classified n,n - dimethyl - p - toluidine no data available optical brightener no data available r espiratory sensitisation nam e species value un ghs classification overall product no test data available. not classified based on com ponent data 2,2' - ethylenedioxydiethyl dim ethacrylate no data available 2 - hy droxypropyl methacrylate n o data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid no data available , - dimethylbenzyl hydroperoxide no data available 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2 ' - phenylacetohydrazide no data available cumene no data available n,n - dimethyl - p - toluidine no data available optical brightener no data available germ cell mutagenicity nam e route value un ghs classification overall product no data available overall germ cell mutagenicity classificationnot classified overall product no test data available. 2,2' - ethylenedioxydiethyl dim ethacrylate in vitro som e positive data exist, but the data are not not classified
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 10 of 17 sufficient for classification 2 - hy dro xypropyl methacrylate no data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid in vitro som e positive data exist, but the data are not sufficient for classification not classified , - dimethylbenzyl hydroperoxide in vivo not mutagenic not classified , - dimethylbenzyl hydroperoxide in vitro som e positive data exist, but the data are not sufficient for classification not classified 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide n o data available 2' - phenylacetohydrazide no data available cumene in vitro not mutagenic not classified cumene in vivo not mutagenic not classified n,n - dimethyl - p - toluidine no data available optical brightener no data available c arcinogenicity nam e route species value un ghs classification overall product no test data available. not classified based on component data 2,2' - ethylenedioxydiethyl dim ethacrylate derm al not carcinogenic not classified 2 - hy droxypropyl methacrylate no data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid ingestion not carcinogenic not classified acrylic acid derm al som e positive data exist, but the data are not sufficient for classification n ot classified , - dimethylbenzyl hydroperoxide no data available 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylacetohydrazide no data available cumene no data available n,n - dimethyl - p - toluidine no data available o ptical brightener no data available reproductive toxicity reproductive and/or developmental effects nam e route value species test result exposure duration un ghs classification overall product no test data available. n ot classified based on com ponent data 2,2' - ethylenedioxydieth yl dimethacrylate ingestion not toxic to reproduction and/or development noael 1 mg/kg/day
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 11 of 17 2 - hy droxypropyl methacrylate no data available m ethacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid inhalation not toxic to reproduction and/or development noael 1.08 mg/l acrylic acid ingestion s om e positive reproductive/deve lopmental data exist, but the data are not sufficient for classification noel 53 mg/kg/day , - dim ethylbenzyl hydroperoxide no data available 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide no data available 2 ' - phenylacetohydrazi de no data available cumene ingestion not toxic to reproduction and/or development noael 769 mg/kg/day cumene inhalation som e positive reproductive/deve lopmental data exist, but the data are not sufficient for classification noel 5.9 mg/l n,n - dimethyl - p - toluidine no data available optical brightener no data available target organ(s) specific target organ toxicity - single exposure nam e route target organ(s) value species test result exposure duration u n ghs classification 2,2' - ethylenedio xydiethyl dim ethacryl ate derm al blood all data are negative noael n/a not classified 2 - hy droxypro pyl methacrylate no data available methacrylic acid, monoester no data available
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 12 of 17 with propane - 1,2 - diol acrylic acid inhalation respirator y irritation som e positive data exist, but the data are not sufficient for classification rd50 1.5 mg/l not classified , - dim ethylbe nzyl hydroperoxi de inhalation central nervous system depressio n m ay cause drowsiness or dizziness noael n/a category 3 , - dim ethylbe nzyl hydroperoxi de inhalation respirator y irritation may cause respiratory irritation irritation positive category 3 1,2 - benzisothiaz ol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylaceto hydrazide no data available cumene inhalation central nervous system depressio n may cause drowsiness or dizziness noael n/a category 3 cumene inhalation respirator y irritation s om e positive data exist, but the data are not sufficient for classification irritation positive not classified cumene ingestion central nervous system depressio n may cause drowsiness or dizziness noael n/a category 3 n,n - dim ethyl - p - toluidine n o data available optical brightener no data available specific target organ toxicity - repeated exposure nam e route target organ(s) value species test result exposure duration un ghs classification overall product no test data available. category 1 based on com ponent data
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 13 of 17 2,2' - ethylenedio xydiethyl dim ethacryl ate derm al kidney and/or bladder som e positive data exist, but the data are not sufficient for classification noael n/a not classified 2 - hy droxypro pyl methacrylate n o data available methacrylic acid, monoester with propane - 1,2 - diol no data available acrylic acid no data available , - dim ethylbe nzyl hydroperoxi de inhalation nervous system | respirator y system s om e positive data exist, but the data are not sufficient for classification not classified , - dim ethylbe nzyl hydroperoxi de inhalation heart | liver | kidney and/or bladder som e positive data exist, but the data are not sufficient for classification n oael 0.03 mg/l not classified 1,2 - benzisothiaz ol - 3(2h) - one 1,1 - dioxide no data available 2' - phenylaceto hydrazide no data available cumene inhalation auditory system | endocrine system s om e positive data exist, but the data are not sufficient for classification noel 24.4 mg/l not classified cumene inhalation hematopoi etic system | liver | nervous system som e positive data exist, but the data are not sufficient for classification noel 4.9 mg/l not classified cumene inhalation ey es som e positive data exist, but the data are not sufficient for classification loel 4.9 mg/l not classified cumene inhalation kidney and/or bladder som e positive data exist, but the data are not sufficien t for noel 4.9 mg/l not classified
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 14 of 17 classification cumene inhalation respirator y system som e positive data exist, but the data are not sufficient for classification noel 24.4 mg/l not classified cumene ingestion kidney and/or bladder som e positive data exist, but the data are not sufficient for classification noel 154 mg/kg/day not classified cumene ingestion heart | endocrine system | hematopoi etic system | liver | respirator y system all data are negative noael 769 mg/kg/day n ot classified n,n - dim ethyl - p - toluidine no data available optical brightener no data available aspiration hazard nam e value un ghs classification overall product no test data available. n ot classified based on com ponent and/or viscosity data 2,2' - ethylenedioxydiethyl dimethacrylate not an aspiration hazard not classified 2 - hy droxypropyl methacrylate not an aspiration hazard not classified m ethacrylic acid, monoester with propane - 1,2 - diol not an aspiration hazard not classified acrylic acid not an aspiration hazard not classified , - dimethylbenzyl hydroperoxide not an aspiration hazard not classified 1,2 - ben zisothiazol - 3(2h) - one 1,1 - dioxide not an aspiration hazard not classified 2' - phenylacetohydrazide not an aspiration hazard not classified cumene aspiration hazard category 1 n,n - dimethyl - p - toluidine not an aspiration hazard not classified o ptical brightener not an aspiration hazard not classified please contact the address or phone number listed on the first page of the sds for additional toxicological information on this m aterial and/or its components. section 12: ecological information the information below may not be consistent with the material classification in section 2 if specific ingredient classifications are mandated by a competent authority. additional information leading to material classification in section 2 is available up on request. in addition, environmental fate and effects data on ingredients may not be reflected in this section because an ingredient is present below the threshold for labelling, an ingredient is not expected to be available for exposure, or the data is considered not relevant to the material as a whole. 12.1. toxicity
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 15 of 17 acute aquatic hazard: ghs acute 3: harmful to aquatic life. chronic aquatic hazard: not chronically toxic to aquatic life by ghs criteria. no product test data available. n o component test data available. 12.2. persistence and degradability no test data available. 12.3 : bioaccum ulative potential no test data available. 12.4. mobility in soil please contact manufacturer for more details 12.5. re sults of the pbt and vpvb assessment no information available at this time, contact manufacturer for more details 12.6. other adverse effects no information available. section 13: disposal considerations 13.1 waste treatm ent methods d ispose of contents/ container in accordance w ith the local/regional/national/international regulations dispose of waste product in a facility permitted to accept chemical waste. the coding of a w aste stream is based on the application of the product by t he consumer. since this is out of the control of 3m, no w aste code(s) for products after use will be provided. please refer to the european waste code (ewc - 2000/532/ec and amendments) to assign the correct w aste code to your waste stream. ensure national and/or regional regulations are com plied w ith and always use a licensed waste contractor. eu waste code (product as sold) 08 04 09* waste adhesives and sealants containing organic solvents or other dangerous substances 20 01 27* p aint, inks, adhesives and resins containing dangerous substances section 14: transportation information gs - 2000 - 4405 - 4, gs - 2000 - 4406 - 2, gs - 2000 - 4407 - 0, gs - 2000 - 4477 - 3, gs - 2000 - 4478 - 1, gs - 2000 - 4496 - 3, gs - 2000 - 4636 - 4, gs - 2000 - 4637 - 2, gs - 2000 - 4695 - 0, gs - 2000 - 4992 - 1, gs - 2000 - 4993 - 9, gs - 2000 - 4994 - 7, gs - 2000 - 4995 - 4, gs - 2000 - 4996 - 2, gs - 2000 - 5025 - 9, gs - 2000 - 5309 - 7, gs - 2000 - 5331 - 1 not hazardous for transportation section 15: regulatory information
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 16 of 17 15.1. s afety, health and environm ental regulations/legislation specific for the substance or m ixture carcinogenicity ingredient cas nbr classification regulation 1,2 - benzisothiazol - 3(2h) - one 1,1 - dioxide 81 - 07 - 2 gr. 3: not classifiable i nternational agency for research on cancer acrylic acid 79 - 10 - 7 gr. 3: not classifiable international agency for research on cancer global inventory status contact 3m for more information. 15.2. chemical safety assessment not applicable s ection 16: other information list of relevant h statem ents h226 flammable liquid and vapour. h242 heating may cause a fire. h301 toxic if swallowed. h302 harmful if swallowed. h304 may be fatal if swallowed and enters airways. h311 t oxic in contact with skin. h314 causes severe skin burns and eye damage. h315 causes skin irritation. h317 may cause an allergic skin reaction. h319 causes serious eye irritation. h330 fatal if inhaled. h331 toxic if inhaled. h335 m ay cause respiratory irritation. h372 causes damage to organs through prolonged or repeated exposure. h373 may cause damage to organs through prolonged or repeated exposure. h400 very toxic to aquatic life. h411 t oxic to aquatic life with long lasting effects. h412 harmful to aquatic life with long lasting effects. list of relevant r - phrases r10 flammable. r20 harmful by inhalation. r21 harmful in contact with skin. r22 harmful if swallowed. r23 t oxic by inhalation. r24 toxic in contact with skin. r25 toxic if swallowed. r33 danger of cumulative effects. r34 causes burns. r35 causes severe burns. r36 irritating to eyes. r37 irritating to respiratory system. r38 irritating to skin. r43 m ay cause sensitisation by skin contact. r48/20 harmful: danger of serious damage to health by prolonged exposure through inhalation.
3m scotch - weld tl70 anaerobic threadlocker __________________________________________________________________________________________ page: 17 of 17 r48/22 harmful: danger of serious damage to health by prolonged exposure if swallowed. r50 very toxic to aquatic organ isms. r51/53 toxic to aquatic organisms. may cause long - term adverse effects in the aquatic environment. r52/53 harmful to aquatic organisms. may cause long - term adverse effects in the aquatic environment. r65 h armful: may cause lung damage if swallowed. r7 may cause fire. revision inform ation: revision changes: sectio 16: uk disclaimer was modified. section 3: composition/ information of ingredients table was modified. copy right was modified. a spiration hazard table w as modified. section 11: acute toxicity table w as m odified. carcinogenicity table w as modified. serious eye damage/irritation table w as modified. germ cell mutagenicity table w as modified. skin sensitisation table w as modified. repr oductive toxicity table was modified. skin corrosion/irritation table w as modified. target organs - repeated table w as m odified. target organs - single table was modified. section 11: health effects - skin information was modified. section 11: health effec ts - inhalation information was modified. section 11: health effects - ingestion information was modified. section 11: health effects - other information was modified. section 5: fire - extinguishing media information was modified. section 5: fire - specia l hazards information was modified. section 6: accidental release personal information was modified. section 6: accidental release environmental information was modified. section 6: accidental release clean - up information was modified. section 7: precautio ns safe handling information was modified. section 7: conditions safe storage was modified. section 8: appropriate engineering controls information was modified. section 13: standard phrase category waste ghs was modified. s ection 12: acute aquatic hazard information was added. section 12: chronic aquatic hazard heading was added. section 12: acute aquatic hazard heading was added. section 12: chronic aquatic hazard information was added. section 8: personal protection - resp iratory information was added. disclaimer: the information on this safety data sheet is based on our experience and is correct to the best of our knowledge at the date of publication, but we do not accept any liability for any loss, damage or injury resul ting from its use (except as required by law). the information may not be valid for any use not referred to in this data sheet or use of the product in combination with other materials. for these reasons, it is important that customers carry out their own test to satisfy themselves as to the suitability of the product for their own intended applications. 3m united kingdom msdss are available at www.3m.com/uk

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